宋飞杰,教授,博士生导师。四川省学术与技术带头人后备人选,学校“狮山学者杰出青年学者”。迄今为止,已在Chem. Soc. Rev.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem. Sci.、Chem. Eur. J.、Chem. Commun.、Org. Lett. 等国际著名学术期刊上发表SCI论文近40篇,其中影响因子>10的论文9篇,5<影响因子<10的论文19篇,3<影响因子<5的论文3篇,参与编写专著2部,申请发明专利1项。论文被引用总数超过一千次,单篇最高引用超过三百次。作为项目负责人承担了包括国家自然科学基金在内的科研项目3项,参与了国家 “863” 计划主题项目1项。
联系方式:
E-mail:fsong@sicnu.edu.cn
QQ:2354313145
办公室地址:化学楼106,实验室化学楼514。热烈欢迎热爱有机化学的同学加入本课题组,让我们一起探索新的领域,享受有机化学带给我们的乐趣。
教育经历:
1999/9–2003/7,理学学士,北京师范大学化学系
2003/9–2008/7,理学博士,中国科学院上海有机化学研究所金属有机化学国家重点实验室,指导教师:刘元红研究员
研究与工作经历:
2008/11–2009/5,美国杜克大学化学系,博士后
2009/5–2011/8,美国北卡罗来纳大学教堂山分校化学系,博士后
2011/11–2012/6,四川大学化学学院,项目制研究助理
2012/7–2014/6,四川大学化学学院,讲师(优秀青年人才)
2014/7–2016/1,四川大学化学学院,副教授
2016/2–现在,四川师范大学化学与材料科学学院,校聘教授
荣获奖励:
2013年度“四川大学优秀青年骨干教师”。
研究方向
过渡金属催化的C–C键断裂重组新方法研究。
承担科研项目:
1)国家自然科学基金面上项目(项目批准号:21772136):过渡金属催化的中环酮C-C单键的选择性活化:中环化合物的高效合成,执行期限2018.1-2021.12,项目负责人。
2)国家自然科学基金青年基金(项目批准号:21202105):金催化的 C–H 键选择性活化及 C–C 交叉偶联反应研究,执行期限2013.1-2015.12,项目负责人。
3)四川大学优秀青年学者科研基金(项目批准号:2013SCU04A42): 金催化的Csp2–H键官能化/环化串联反应:环状化合物的高效合成, 执行期限2013.10-2016.12, 项目负责人。
4)四川大学青年教师科研启动基金(项目批准号:2012SCU11077):金催化的基于 C–H 键活化的 C–C 交叉偶联反应研究,执行期限2012.10-2013.12,项目负责人。
5) 国家 “863” 计划主题项目(项目批准号:2013AA031900):新型纳米能源材料及器件关键制备技术,2013.1-2015.12,项目主要参与者。
代表性成果:
1、已发表论文目录
1) Feijie Song, Ting Gou, Bi-Qin Wang, Zhang-Jie Shi.* Catalytic Activations of Unstrained C–C Bond Involving Organometallic Intermediates. Chem. Soc. Rev., 2018, 47, 7078-7115. (IF = 40.18)
2) Wei Li, Feijie Song, Jingsong You.* Oxidant-Controlled Catalytic Transformations of Phenols with Unexpected Cleavage of Aromatic Rings. Chem. Eur. J., 2015, 21 (40), 13913–13918. (IF = 5.696)
3) Shuai Zhang, Yuanhong Ma, Feijie Song,* Jingsong You.* Gold-Catalyzed Cascade C–H/C–H Cross-Coupling/Cyclization/Alkynylation: An Efficient Access to 3-Alkynylpyrroles. Org. Biomol. Chem., 2015, 13 (21), 5867–5870 (IF = 3.562)
4) Qian Wu, Chenglong Du, Yumin Huang, Xingyan Liu, Zhen Long, Feijie Song, Jingsong You.* Stoichiometric to Catalytic Reactivity of the Aryl Cycloaurated Species with Arylboronic Acids: Insight Into the Mechanism of Gold-Catalyzed Oxidative C(sp2)–H Arylation. Chem. Sci., 2015, 6 (1), 288–293. (IF = 8.601)
5) Xingyan Liu, Gaocan Li, Feijie Song, Jingsong You.* Unexpected Regioselective Carbon–Hydrogen Bond Activation/Cyclization of Indolyl Aldehydes or Ketones with Alkynes to Benzo-Fused Oxindole. Nature commun., 2014, 5, 5030. (IF = 10.742)
6) Yuanhong Ma, Shuai Zhang, Shiping Yang, Feijie Song,* Jingsong You.* Gold-Catalyzed Cascade C(sp3)–H/C(sp)–H Coupling/Cyclization/Oxidative Alkynylation: A Powerful Strategy for the Synthesis of 3-Alkynyl Polysubstituted Furans. Angew. Chem. Int. Ed., 2014, 53 (30), 7870–7874. (IF = 11.336)
7) Zhijie She, Yang Shi, Yumin Huang, Yangyang Cheng, Feijie Song,* Jingsong You.* Versatile Palladium-Catalyzed C–H Olefination of (Hetero)arenes at Room Temperature. Chem. Commun., 2014, 50 (90), 13914–13916. (IF = 6.718)
8) Lei Yang, Yuanhong Ma, Feijie Song,* Jingsong You.* Silver-Catalyzed One-Pot Cyclization/Fluorination of 2-Alkynylanilines: Highly Efficient Synthesis of Structurally Diverse Fluorinated Indole Derivatives. Chem. Commun., 2014, 50 (23), 3024–3026. (IF = 6.718)
9) Ningjie Wu, Feijie Song, Lipeng Yan, Juan Li, Jingsong You.* Transition-Metal-Catalyzed C–H Bond Functionalizations: Feasible Access to a Diversity-Oriented β-Carboline Library. Chem. Eur. J., 2014, 20 (12), 3408–3414. (IF = 5.696)
10) Mingliang Li, Jiaxing Dong, Xiaolei Huang, Kaizhi Li, Qian Wu, Feijie Song, Jingsong You.* Nickel-Catalyzed Chelation-Assisted Direct Arylation of Unactivated C(sp3)–H Bonds with Aryl Halides. Chem. Commun., 2014, 50, 3944–3946. (IF = 6.718)
11) Gaocan Li, Feijie Song, Di Wu, Jingbo Lan, Xingyan Liu, Jie Wu, Shuaijun Yang, Dan Xiao, Jingsong You.* Cation-Anion Interaction-Directed Molecular Design Strategy for Mechanochromic Luminescence. Adv. Funct. Mater., 2014, 24 (6), 747–753. (IF = 10.439)
12) Yuanhong Ma, Jingsong You,* Feijie Song.* Facile Access to 3-Acylindoles through Palladium-Catalyzed Addition of Indoles to Nitriles: The One-Pot Synthesis of Indenoindolones. Chem. Eur. J., 2013, 19 (4), 1189–1193. (IF = 5.696)
13) Luo-Qiang Zhang, Shiping Yang, Xiaolei Huang, Jingsong You, Feijie Song.* Aerobic Ru-Catalyzed Direct C2-Olefination of N-Heteroarenes with Alkenes Directed by a Removable N-Dimethylcarbamoyl group. Chem. Commun., 2013, 49 (78), 8830–8832. (IF = 6.718)
14) Fan Yang, Zhigang Wang, Feijie Song,* Xingyan Liu, Jingbo Lan, Jingsong You.* One-Step Synthesis of Imidazoline-Containing Macrocycles and Their Complexation with Fullerenes C60 and C70. Chem. Commun., 2013, 49 (53), 5975 –5977. (IF = 6.718)
15) Shuai Zhang, Feijie Song,* Dongbing Zhao, Jingsong You.* Tandem Oxidation–Oxidative C–H/C–H Cross-Coupling: Synthesis of Arylquinones from Hydroquinones. Chem. Commun., 2013, 49 (40), 4558–4560. (IF = 6.718)
16) Fan Yang, Feijie Song,* Wei Li, Jingbo Lan, Jingsong You.* Palladium-Catalyzed C–H Activation of Anilides at Room Temperature: ortho-Arylation and Acetoxylation. RSC Adv., 2013, 3 (25), 9649–9652. (IF = 3.708)
17) Xiaolei Huang, Jingsheng Huang, Chenglong Du, Xingyi Zhang, Feijie Song, Jingsong You.* N-Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of ortho-Alkenylated Tertiary Anilines. Angew. Chem. Int. Ed., 2013, 52 (49), 12970–12974. (IF = 11.336)
18) Kaizhi Li, Guangying Tan, Jingsheng Huang, Feijie Song, Jingsong You.* Iron-Catalyzed Oxidative C–H/C–H Cross-Coupling: An Efficient Route to α-Quaternary α-Amino Acid Derivatives. Angew. Chem. Int. Ed., 2013, 52 (49), 12942–12945. (IF = 11.336)
19) Jiaxing Dong, Zhen Long, Feijie Song, Ningjie Wu, Qiang Guo, Jingbo Lan, Jingsong You.* Rhodium or Ruthenium-Catalyzed Oxidative C–H/C–H Cross-Coupling: Direct Access to Extended π-Conjugated Systems. Angew. Chem. Int. Ed., 2013, 52 (2), 580–584. (IF = 11.336)
20) Bo Liu, Yumin Huang, Jingbo Lan, Feijie Song, Jingsong You.* Pd-Catalyzed Oxidative C–H/C–H Cross-Coupling of Pyridines with Heteroarenes. Chem. Sci., 2013, 4 (5), 2163–2167. (IF = 8.601)
21) Dongbing Zhao, Qian Wu, Xiaolei Huang, Feijie Song, Taiyong Lv, Jingsong You.* A General Method to Diverse Cinnolines and Cinnolinium Salts. Chem. Eur. J., 2013, 19 (20), 6239–6244. (IF = 5.696)
22) Taiyang Lv, Lei Yang, Yinsong Zhao, Feijie Song, Jingbo Lan, Jingsong You,* Ge Gao.* One-Pot Synthesis of Diarylimidazolium Salts from 1H-Imidazole. Chin. Chem. Lett., 2013, 24, 773–776. (IF = 1.178)
23) Feijie Song, Cheng Wang, Wenbin Lin.* Chiral Porous Metal-Organic Frameworks with Dual Active Sites for Sequential Asymmetric Catalysis. Proc. R. Soc. A, 2012, 468 (2143), 2035–2052. (IF = 1.998)
24) Zhen Wang, Feijie Song, Yinsong Zhao, Yumin Huang, Lei Yang, Dongbing Zhao, Jingbo Lan, Jingsong You.* Elements of Regiocontrol in the Direct Heteroarylation of Indoles/Pyrroles: Synthesis of Bi- and Fused Polycyclic Heteroarenes via Twofold or Tandem Fourfold C–H Activation. Chem. Eur. J., 2012, 18(52), 16616–16620. (IF = 5.696)
25) Bo Liu, Jian Li, Feijie Song, Jingsong You.* Palladium-Catalyzed Direct Arylation of N-Heteroarenes with Arylsulfonyl Hydrazides. Chem. Eur. J., 2012, 18 (35), 10830–10833. (IF = 5.696)
26) Yumin Huang, Feijie Song, Zhen Wang, Peihua Xi, Ningjie Wu, Zhigang Wang, Jingbo Lan, Jingsong You.* Dehydrogenative Heck Coupling of Biologically Relevant N-Heteroarenesswith Alkenes: Discovery of Fluorescent Core Frameworks. Chem. Commun., 2012, 48, 2864–2866. (IF = 6.718)
27) Teng Zhang, Feijie Song, Wenbin Lin.* Blocking Bimolecular Activation Pathways Leads to Different Regioselectivity in Metal–Organic Framework Catalysis. Chem. Commun., 2012, 48 (70), 8766–8768. (IF = 6.718)
28) Feijie Song, Cheng Wang, Wenbin Lin.* A Chiral Metal-Organic Frameworks for Sequential Asymmetric Catalysis. Chem. Commun., 2011, 47 (29), 8256–8258. (IF = 6.718)
29) Hao Li, Feijie Song, Ross A. Widenhoefer.* Gold (I)-Catalyzed Intramolecular Hydroamination of N-Allylic, N'-Aryl Ureas to Form Imidazolidin-2-ones. Adv. Synth. Catal., 2011, 353 (6), 955–962. (IF = 5.542)
30) Feijie Song, Cheng Wang, Joseph M. Falkowski, Liqing Ma, Wenbin Lin.* Isoreticular Chiral Metal−Organic Frameworks for Asymmetric Alkene Epoxidation: Tuning Catalytic Activity by Controlling Framework Catenation and Varying Open Channel Sizes. J. Am. Chem. Soc., 2010, 132 (43), 15390–15398. (IF = 11.444)
31) Yuhua Lu, Feijie Song, Xueshun Jia, Yuanhong Liu.* Transition Metal-Catalyzed Synthesis of Furan Derivatives. Prog. Chem., 2010, 22 (1), 58–70. (IF = 0.714)
32) Feijie Song, Yuanhong Liu.* A Facile Approach to Spirocyclic Butenolides through Cascade Cyclization/ Oxidative Cleavage Reactions of (Z)-Enynols Catalyzed by Gold under Dioxygen Atmosphere. J. Organomet. Chem., 2009, 694 (4), 502–509. (IF = 2.302)
33) Xiangwei Du, Feijie Song, Yuhua Lu, Haoyi Chen, Yuanhong Liu.* A General and Efficient Synthesis of Substituted Furans and Dihydrofurans via Gold-catalyzed Cyclization of (Z)-2-En-4-yn-1-ols. Tetrahedron, 2009, 65 (9), 1839–1845. (IF = 2.817)
34) Shenghai Guo, Feijie Song, Yuanhong Liu.* Gold-Catalyzed Direct Amination of Allylic Alcohols. Synlett, 2007 (6), 964–968. (IF = 2.463)
35) Shenghai Guo, Hao Zhang, Feijie Song, Yuanhong Liu.* Studies on the Zirconium-Mediated Alkyne–Aldehyde Coupling Reactions: A Facile Synthesis of Stereodefined Allylic Alcohols and (Z)-2-En-4-yn-1-ols. Tetrahedron, 2007, 63 (9), 2009–2018. (IF = 2.817)
36) Yuanhong Liu,* Feijie Song, Shenghai Guo. Cleavage of a Carbon-Carbon Triple Bond via Gold-Catalyzed Cascade Cyclization/Oxidative Cleavage Reactions of (Z)-Enynols with Molecular Oxygen. J. Am. Chem. Soc., 2006, 128 (35), 11332–11333. (IF = 11.444,第一作者为导师)
37) Yuanhong Liu,* Feijie Song, Zhiquan Song, Meina Liu, Bin Yan. Gold-Catalyzed Cyclization of (Z)-2-En-4-yn-1-ols: Highly Efficient Synthesis of Fully Substituted Dihydrofurans and Furans. Org. Lett., 2005, 7 (24), 5409–5412. (IF = 6.324,第一作者为导师)
38) Yuanhong Liu,* Feijie Song, Liqing Cong. A Facile Zr-Mediated Approach to (Z)-Enynols and Its Application to Regio- and Stereoselective Synthesis of Fully Substituted Dihydrofurans. J. Org. Chem., 2005, 70 (17), 6999–7002. (IF = 4.638,第一作者为导师)
2、发明专利
1) 高戈、吕太勇、游劲松、吴迪、兰静波、宋飞杰、陈世刚:咪唑类鎓盐的合成新方法,中国,专利申请号201210372909.0,申请日期 2012/9/30。
3、专著目录
1) Gold-Catalyzed Addition of Oxygen Nucleophiles to C–C Multiple Bonds. Ross A. Widenhoefer,* Feijie Song. in Catalyzed Carbon-Heteroatom Bond Formation, Yudin, A. K. Ed.: Wiley-VCH: Wienheim, 2011, 463–492.
2) Gold-Catalyzed Addition of Nitrogen and Sulfur Nucleophiles to C–C Multiple Bonds. Ross A. Widenhoefer,* Feijie Song. in Catalyzed Carbon-Heteroatom Bond Formation, Yudin, A. K. Ed.: Wiley-VCH: Wienheim, 2011, 437–461.
【编辑:化学】
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